Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ2 S,S′]platinate(II)
نویسندگان
چکیده
In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry ) is coordinated by two S,S'-bidentate N-(2,5-dichloro-phenyl-sulfon-yl)dithio-carbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C-H⋯O inter-action is observed, as well as electrostatic attraction between the oppositely charged ions.
منابع مشابه
Bis(tetraphenylphosphonium) bis[N-(phenylsulfonyl)dithiocarbimato-κ2 S,S′]platinate(II) monohydrate
The asymmetric unit of the title compound, (C(24)H(20)P)(2)[Pt(C(7)H(5)NO(2)S(3))(2)]·H(2)O, consists of two tetra-phenyl-phospho-nium cations, two half bis-[N-(phenyl-sulfon-yl)dithio-carbim-ato]platinate(II) dianions and one water mol-ecule. The anions are completed by crystallographic inversion symmetry associated with the central Pt(II) ion. The Pt(II) ion is doubly S,S'-chelated by two sym...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010